Chapter-10 Haloalkanes and Haloarenes MCQs

Q 41.: What is DDT among the following ?

(A) A fertilizer

(B) Non-biodegradable pollutant

(C) Biodegradable pollutant

(D) Greenhouse gas

Option – B

Q 42.: When you heat chloroform with silver powder _____ is formed

(A) Methane

(B) Ethane

(C) Ethene

(D) Ethyne

Option – D

Q 43.: Iodo-alkane is obtained by the reaction of bromo-alkane or chloro-alkane with solution of NaI prepared in dry acetone. This reaction is known as ____

(A) Finkelstein reaction

(B) Swarts Reaction

(C) Gattermann reaction

(D) Balz-schiemann reaction

Option – A

Q 44.: Which branched chain isomer of the hydrocarbon with molecular mass 72 u gives only one isomer of mono substituted alkyl halide ?

(A) Neopentane

(B) Isohexane

(C) Neohexane

(D) Tertiary butyl chloride

Option – A

Q 45.: In dihalide if both halogen are combined with adjacent carbon atom then such halide are known as ___

(A) Aryl halide

(B) Geminal halide

(C) Vicinal halide

(D) All of these

Option – C

Q 46.: What are nucleophilic reagents according to Lewis theory ?

(A) Lewis Acid

(B) Lewis Base

(C) Positive ion

(D) Neutral Molecules

Option – B

Q 47.: Which of the following compound is obtained by Sandmeyer reaction ?

(A) Benzyl chloride

(B) Aniline

(C) Chlorobenzene

(D) Phenol

Option – C

Q 48.: If a molecule has ‘n’ number of different chiral centres, then, how many possible stereoisomers will it have ?

(A) 2n 

(B) n2

(C) 2n+1

(D) 2n–1

Option – A

Q 49.: Which of the following is a free radical Halogenation reaction ?

(A) Benzene converted to bromobenzene

(B) Phenol converted to chlorobenzene

(C) Benzene diazonium chloride converted to chlorobenzene

(D) Propane converted to 1-chloropropane and 2-chloropropane

Option – D

Q 50.: A molecule having 3 different chiral carbon atoms, how many stereo-isomers it will have ?

(A) Three

(B) Six

(C) Eight

(D) Nine

Option – C

Q 51.: Which of the following is obtained by hydrolysis of ethyl-magnesium bromide ?

(A) CH3-CH3

(B) CH3-CH=CH2

(C) CH4

(D) CH2=CH2

Option – A

Q 52.: Which two reagents are required to produce D.D.T. ?

(A) Chloral and chlorobenzene

(B) Chloroform and chlorobenzene

(C) CCl4 and chlorobenzene

(D) Chloral chloroform

Option – A

Q 53.: How many chiral carbon atoms are there in 1-chloro-2, 5-dimethyl cyclohexane ?

(A) Zero

(B) One

(C) Two

(D) Three

Option – D

Q 54.: Which of the following compounds causes red rashes, if it comes in direct contact with skin ?

(A) CCl4

(B) CHCl3

(C) CH2Cl2

(D) CH3Cl

Option – C

Q 55.: What is the correct relation for SN2 reaction ?

(A) rate = k [R]2 

(B) rate = k [Nu:]2 

(C) rate = k [R] [Nu:]

(D) rate = k [R]2 [Nu:]2

Option – C